离子化策略构建木聚糖基室温磷光材料的研究

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作者简介：，在读硕士研究生；主要从事林木生物质室温磷光材料等方面的研究。

关键词：室温磷光；木聚糖；定向氧化还原；离子化；防伪中图分类号：TS79 文献标识码：A DOI：10.11980/j.issn.0254-508X.2025.12.003

Ionization Strategy for Constructing Xylan-based Room-temperature Phosphorescent Materials

LI Minzhao1YAN Zhengxu’ZHANG Xinyuan²LYU Baozhong1*PENG Fengl.* （1.Beijing KeyLab of Lignocellulosic Chemistry，Beijing Forestry University，Beijing，; 2.Naiqiu Ruo（Chengde）Biotechnology Co.，Ltd.，Chengde，Hebei Province，O67500; 3.StateKeyLab ofEfficientProductionofForest Resources，Beijing，） （ E-mail：lvbaozhong@bjfu.edu.cn；fengpeng@bjfu.edu.cn）

Abstract：Inthispaper，xylan-basedhmicelulosewasusedasrawmaterial.Throughdirectedoxidation-reductionreactions，xylanwas convertedintowater-solublering-extealprimaryhydroxyxylan（RDAX）.Anionicbondingstrategyasmploydtoanchorsodiumaryl carboxylatechomophoreswithonjugatedstructuresontoteigidxylanbackbone，esultingintepreparatioofolor-tunable，log-life timexylan-basedoom-temperatureposhoresece（RTmaterialsExprimentsdemonstratdthatylanprovidedpletiveolinkingsitesandarigidenvironmentthroughdirectedredoxmolecularrestructuring.Therigidhydrogenbondnetworkformedbyrestructuredxylansyeisiallyablstripleteisviaoonding，sultinginaposporeselifeeofuto93msfore material.Additionally，efleibleanti-counterfeitingfidalsoensucesfullyevelopdbyutilingthterolasiciyf RDAX.

Key words：room-temperature phosphorescence；xylan；directed oxdation-reduction；ionization；anti-counterfeiting

室温磷光（RTP）是一种独特的发光现象，其以激发三重态储存能量，并以光的形式缓慢释放能量2]。（剩余12273字）