不同条件下制备的钌钛阳极电催化析氯的研究

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中图分类号：0646.542 文献标识码：A DOI：10.7535/hbkd.2025yx06006

Abstract：Inordertoaddress theisuesof lowenergyutilizationrateandhigh energyconsumptioninthechlor-alkali industry，a method using hydrosol to prepare ruthenium-titanium （ ⋅Ru-Ti） anode was proposed to enhance catalytic efficiency. TheRu-Tianodes underdiferentconditions were prepared byusing thehydrosol method.The efectsoftheconcentrationof hydrochloric acid precursor，the molar ratio of Ru -Tiand the number of coating layers on the chlorine evolution performance of the anodeswere studiedby X-raydifraction（XRD），linear sweep voltammetry（LSV），cyclic voltammetry（CV）and electrochemical impedance spectroscopy （EIS）.The results show that the Ru -Ti anode prepared under the conditions of a precursor solution with a hydrochloric acid concentration of 1.5mol/L ，aRu-Ti molar ratio of 3：7 ，and 10 coating layers has the lowest chlorine evolution potential of 1.09V vs.SCE，which is much lower than the chlorine evolution potential of the graphite electrode 1.25V vs.SCE）.The titanium-based Ru-Ti anode prepared by the aqueous sol-gel method under certain conditionshasexcelentelectrocatalyticchlorineevolutionperformance，oferingvaluableinsightsforthedevelopmentofhigh performance chlorine evolution anode materials.

Keywords：electrochemistry；chlor-alkali industry；ruthenium-titanium anode；chlorine evolutionreaction；electrocatalysis

氯碱工业是最大的化学工业之一[1-3]，其主要产品有氯气、氢气、氢氧化钠，被广泛应用于农业、纺织、建材、电力、冶金、轻工业、石油化工等行业[4-6]。（剩余13769字）