悬浮床加氢尾油气化炭黑的理化性质

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文章编号：1003-9015（2025）04-0732-11

中图分类号：TQ021 文献标志码：A DOI：10.3969/j.issn.1003-9015.2025.04.017

Abstract：Inorder to studythe physicalandchemical properties of soot in slurry-bed hydrogenation tailoil gasification，using elemental analysis，scanning electron microscopy （SEM），transmisson electron microscopy （TEM）， X-ray diffraction （XRD），thermogravimetric analysis（TGA），Fourier transform infrared spectroscopy（FT-IR）， and X-ray fluorescence spectroscopy （XRF）were used to systematically characterize and analyze soot from suspensionbedhydrogenationtailoil gasification.Theresultsshow thatthecontentoffixedcarbon，volatilemater，and ash in soot are 43.73% ， 19.63% ，and 36.64% ，respectively；TheC/Hratio is3.93，whichbelongsto immature soot；Thesurface of soot exhibits collapse，roughness，and random distribution of irrgular small pores.In adition，most soot has a more "hollow" structures；Soot ash exists inthe formof aggregates，with the main components （204号 V205 ， Mo03 ，and NiO accounting for 53.33% ， 27.13% ，and 12.83% ，respectively. Therefore，soot can be regardedas atarget for vanadium，nickel，andnickel resource recovery；The surface of soot adsorbs soluble organic matter and contains a certain amount of functional groups such as C-O and—OH；The specific surface area and pore volume of soot are only 42.05m2⋅g-1 and 0.13cm3⋅g-1 ，respectively； Soot shows low combustion reactivity （ S= （20 6.9×10-12min-2⋅C-3， ，which may be due to its internal structural characteristics，which hinders the diffsion and adsorption of oxygen molecules on its surface，thus affecting the speed and effciency of combustion reaction.

Key words： soot； slurry-bed hydrogenation;gasification；morphology； oxidation reactivity

1前言

随着人类社会的发展和世界能源消耗的日益增长，如何高效利用重质油（例如渣油）已成为国际关注的焦点[1]。（剩余15283字）