静电纺丝技术制备 PW12/ZrO2 纳米纤维及其氧化脱硫性能

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中图分类号：O611 文献标志码：Adoi： 10.3969/j .issn.1673-5862.2025.03.001

Synthesis of PW12/ZrO2 nanofibers by electrospinning and their oxidative desulfurization performance

MA Wenwen 1，2 ， ZHANG Danyi1，2 ， MA Jiayang 1，2 ， WANG Rui1，2

ZHAO Zhen1，2，3

（1.College of Chemistry and Chemical Engineering，Shenyang Normal University，Shenyang 110034，China; 2.Insitituteof Catalysis for Energy and Environment，Shenyang Normal University，Shenyang l1oo34，China; 3.State Key Laboratory of Heavy Oil Processing，China University of Petroleum，Beijing lO2249，China）

Abstract： In this paper， PW12/ZrO2 nanofiber catalysts with different amount of PW12 were prepared using N，N-dimethylformamide，chloro-zirconium oxide， PW12 and polyvinylpyrrolidone as raw materials by electrospinning technology. The structure，morphology and composition of （20 PW12/Zr2 nanofiber catalysts were analyzed via variety of characterization techniques， such as X-ray diffraction（XRD），scanning electron microscope（SEM） and so on. At the same time，the catalytic oxidation desulfurization performance was also investigated. The results showed that 0.02g of 40 wt. % PW12/ZrO2 nanofiber catalyst，when the O/s was 6：1 at 70°C ，hada conversion rate of dibenzothiohene（DBT）over 98% within 120min . Moreover，these catalysts have good recyclability. Such catalytic materials exhibit excellent catalytic stability and have great potential for industrial application.

Key words ： zirconia; phosphotungstic heteropoly acid;electrostatic spinning，oxidative desulfurization

如何解决燃料里含硫化合物引发的环境问题已然成为全球共同面临的挑战。（剩余5825字）