用于图案化打印的聚合物稳定液晶材料

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中图分类号: 0753+.2 文献标识码:A doi:1O.37188/CJLCD.2025-0119 CSTR:32172.14.CJLCD.2025-0119

Polymer-stabilized liquid crystals for pattern inkjet printing

ZHANG Zhili1/², SUN Yi1, HUANG Wenbin23, ZHOU Xiaohong ⋅2,3,4 (2号YU Zhongwei¹,HUANG Yanyan1

(1. School of Physical Science and Technology,Nantong University,Nantong 226Ool,China;

2. Collaborative Innouation Center of Suzhou Nano Science and Technology, School ofOptoelectronic Science and Engineering,Soochow University,Suzhou 2l5oO6,China;

3. Key Lab of Aduanced Optical Manufacturing Technologies of Jiangsu Province, Key Lab ofModern Optical Technologies of Education Ministry of China, Soochow University, Suzhou 215006,China;

4.Weiyeda Technology (Jiangsu) Co.Ltd.,Nantong 226Ool,China)

Abstract: The conventional paterning of PSCLC films relies on prefabricated photomasks or complex micro/ nano fabrication processes,which are costly and limited flexibility,thus restricting their applications in personalized optical devices.In this work,a drop-on-demand inkjet printing technique is employed to achieve rapid and eficient paterning,enabling programmable and highly designable liquid crystal patterns.A birefringent film is introduced to enhance optical modulation eficiency and realize gradient color variations.Experimentally,the reflection peaks of red,green,and blue PSCLC materials are centered at 680nm , 550nm ,and 490nm ,respectively,and all enter a scattering state under applied DC voltages,demonstrating excellent electro-optical responsiveness.By optimizing the viscosity of the liquid crystal solution and the driving waveform,uniform PSCLC pixel arays with a minimum pixel size of 60 (20号 μm are successfully fabricated,verifying the feasibility of the inkjet printing process.This low-cost and scalable patterning method significantly improves the precision of PSCLC patterning.It also expands their potential applications in flexible displays,smart photonic devices,and tunable optical elements.

Key words: cholesteric liquid crystal; inkjet printing;spectrum tuning;electric driving

1引言

液晶由于固有的光学各向异性、自组装能力和对外部刺激的灵敏响应,在防伪、光调控、先进显示、智能窗户[1-5]等多个领域取得广泛应用。(剩余10509字)

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