3种氯代烷基有机磷酸酯 对土壤白符跳(Folsomiacandida)的毒性效应
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中图分类号：X171.5 文献标志码：A 文章编号：1672-2043（2025）12-3061-09 doi：10.11654/jaes.2024-1108
xic effects of three chlorinated alkyl organic phosphate esters on Folsomia candida in s（
LIUPeng，WEIXinni，SHI Jiayue，GAO Ge ，ZHU Hang ，ZHAOLong，DANGXiuli （1.CollegofandndEviontangAgricualUvesitytioalEginLboratoforntUlzatifl andFertilizerResoces，rtastKeyboatoryofseationdImproventofCultiatedand，nstryfgicultudual Affairs，Shenyang866，Cin;.CenterfornvioentalHealthRiskAsessentandesearch，CneseResearchAcadeyof Environmental Sciences，Beijing 10oo12， China）
Abstract：Toarifthoxicitydfrencsofdierenthloroalkygaicpospatestesonsoidwelingivertebatesrngtail survivalrateseproductionumber，andchangesinantioxidantezeactivityweremeasuedasteevaluatioendpointstostudythe toxicity effects of three exogenous organic phosphate esters（tri（2-chloroethyl） phosphate ester（TCEP），tri - （ 2 -chloropropyl）phosphate ester（TCPP），andtri（1，3-dichloro-2-propyl）phosphateester（TDCPP））onmodelorganismFolsomiacandidainblack.Tersults showedthattheLCsmedianlethalconcetration）ofTCEPandTCPforacutetoxicity（7days）toFolsomiacandidawerelessthan1000 mg·kg-1 ，respectively，while theLC5o of TDCPP exceeded 1 000mg⋅kg-1 .The EC5o（half effect concentration） of TCEP，TCPP，and TDCPP for the chronic toxicity of Folsomia candida（28 days） were 52.8， 9.0mg⋅kg-1 ，and 12.3mg⋅kg-1 ，respectively. TCPP had a significant inducing effect on SOD activity （ P<0.05| ）in chronic toxicity，and the activity of CATwas most affected by TDCPP，showing an inhibitory effect（P-1） ，while itinhibits them at a high concentration（ 48mg⋅kg-1） .The results of this study provide data support and theoretical basis for evaluating the ecological risksofchloroalkylorganicphospatestersonsoilinvertebates.Basedonetoxicitytresolds，itcanbeinferredthatteoic toxicityof the three chloroalkylorganic phosphate esters decreased in the following order：TCPP>TDCPP>TCEP. Keywords：organic phosphate esters; invertebrate; toxic effects; enzyme activity; soil
有机磷酸酯（OPEs）根据其取代基不同分为烷基、芳香基和卤代烷基磷酸酯。（剩余22063字）
