萘甲醛缩甘氨酸席夫碱配基结构的键合型高分子-稀土配合物发光材料的制备及其发光性能研究

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中图分类号：0631文献标识码：A

Preparation and Exploration of Luminescence Property of Polymer-Rare Earth Complexes with Naphthalaldehyde Glycine Schiff Base Ligand

WANG Dong'， ZHANG Dandan²*，GENG Zhenhuan²， SUN Hongguang² （1.Schoolof InformationandElectrical Enginering，Hebei UniversityofEngineering，Handan，HebeiO56038，China; 2.School of Materials Science and Engineering，Hebei University of Engineering，Handan，Hebei O56038，China）

Abstract： In order to prepare high-performance bonded polymer-rare earth complex luminescent materials and explore the relationship between their structure and luminescent properties，functionalized polysulfone （PSF-NGly） containing naphthalene formaldehyde condensation glycine Schiff base ligand structure was prepared through three steps of macromolecular reactions. The products of each step were characterized byinfrared，proton nuclear magnetic resonance，ultravioletand ninhydrin colorimetric methods. The obtained PSF-NGly was coordinated with rare earth Eu（II） ions to form the polymer-rare earth complex PSF-（NGly） -Eu（II）. The luminescent properties of PSF-（NGly） -Eu（ Il ）were de3 3 termined by fluorescence spectroscopy. The results showed that the naphthalene formaldehyde condensation glycine Schiff base group was successfully bonded to the polysulfone side chain，and the macromolecular ligand PSF-NGly produced an “Antenna” effect on the Eu（II） ion．The complex PSF- （NGly）3 1 Eu（II） had excellent luminescent properties.

Key words：bonding polymer-rare earth complex；naphthalene formaldehyde glycine； Schiff base li-gand;Antenna effect

键合型高分子-稀土配合物发光材料，具有发光性能优异、稳定性好、加工性能良好、易于功能化等优点，使其成为极具发展潜力的优良材料[1-4]。（剩余11094字）