有机小分子荧光探针结合静电纺丝用于爆炸物检测研究进展

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中图分类号:0482.31 文献标识码:ADOI:10.37188/CJL.20240235 CSTR:32170.14.CJL.20240235
Advances in Integration of Organic Small Molecule Fluorescent Probes with Electrospinning Techniques for Detection of Explosives
CHENGLeqin,TAOYunqi,ZHANGYuewei,YUXue* (SchoolofChemistryandPharmaceuticalEngineering,JilinInstituteofChemicalTechnology,Jilin32O2,China) *Corresponding Authors,E-mail:zhangyueweichem@163.com;dongjibinghuayuxue@163.com
Abstract: In recent years,advancements inthe preparation and concealmentof explosives have presented increasinglysignificantchallengesfortheirdetection.Organicsmal-moleculefluorescentprobeswithhighsensitivity,highselectivityandlowdetectionlimithavebecomewidelyused inexplosiveidentification.However,theidentificationof explosivesbythesefluorescentprobesoftenneedstobecariedoutinsolution,resultinginasignificantlimitationof theirapplication.Electrospining representsahighly efective techniqueforthe fabricationof nanofibers characterized bycontrollable diameters and uniform morphologies.Fluorescent nanofiber membranes withtheadvantages of easy portability,goodreproducibilityand low detection limit were prepared by combining fluorescent probes with electrospinning technology,whichefectivelybroadened theapplicationoffluorescentprobesinthedetectionofexplosives.Inthis paper,the structure offluorescence sensing unitsoforganic small molecule materials is clasified,and theeffectsof organic smallmolecule fluorescent nanofiber membrane sensors on common explosives such as trinitrotoluene(TNT), trinitrophenol(TNP),2,4-dinitrotoluene(DNT)and cyclotrimethylene trinitramine(RDX),triacetone triperoxide (TATP),etc.are summarized,give guidance for the design of electrospun fluorescent nanofiber membranes inactual explosives detection,and providenew ideas forthe practicalapplicationoffluorescentprobes incomplex environments.
KeyWords:fluorescent probe;electrospinning;explosive detection;nano-thin film fibers
1引言
爆炸恐怖袭击事件严重威胁世界安全与社会稳定,爆炸物的泄露还会对人类健康、生态环境造成直接危害,因此,爆炸物的检测已成为当前国际安全中密切关注的问题之一[-3]。(剩余22966字)